PHIBRO ENERGY USA, INC. -- DIESEL FUEL -- 9140-01-313-7776
===================== Product Identification ===================== Product ID:DIESEL FUEL MSDS Date:01/31/1994 FSC:9140 NIIN:01-313-7776 === Responsible Party === Company Name:PHIBRO ENERGY USA, INC. Address:500 DALLAS AVE, SUITE 3200 City:HOUSTON State:TX ZIP:77002 Country:US Info Phone Num:713-646-5135 Emergency Phone Num:713-923-6641, CHEMTREC 800-424-9300 Preparer's Name:SUE BOTTOM CAGE:0V310 === Contractor Identification === Company Name:PHIBRO ENERGY USA INC Address:500 DALLAS AVE SUITE 3200 Box:City:HOUSTON State:TX ZIP:77002 Country:US Phone:713-923-6641, CHEMTREC800-424-9300 CAGE:0V310 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM DISTILLATE, ALIPHATIC AND AROMATIC HYDROCARBONS (VARYING FROM C9 TO C20), CONTAING ALSO INGREDIENT #2 TO 7. Fraction by Wt: BALANCE Other REC Limits:NONE SPECIFIED OSHA PEL:400 PPM NAPHTHA TWA Ingred Name:N-OCTANE CAS:111-65-9 RTECS #:RG8400000 Fraction by Wt: <1-2% Other REC Limits:NONE SPECIFIED OSHA PEL:300 PPM TWA 1989 ACGIH TLV:300 PPM/375STEL;9394 Ingred Name:N-NONANE CAS:111-84-2 RTECS #:RA6115000 Fraction by Wt: <1-3% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM ACGIH TLV:200 PPM; 9192 Ingred Name:NAPHTHALENE (SARA III) CAS:91-20-3 RTECS #:QJ0525000 Fraction by Wt: <1-3% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9394 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:HEXANE ISOMERS (OTHER THAN N-HEXANE) Fraction by Wt: <1-3% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM ACGIH TLV:500 PPM Ingred Name:N-HEXANE CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: <1-2% Other REC Limits:NONE RECOMMENDED OSHA PEL:50 PPM 1989 ACGIH TLV:50 PPM; 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:N-HEPTANE CAS:142-82-5 RTECS #:MI7700000 Fraction by Wt: <1-2% Other REC Limits:NONE RECOMMENDED OSHA PEL:400 PPM TWA 1989 ACGIH TLV:400 PPM/500STEL;9394 Ingred Name:HYDROGEN SULFIDE (SARA III) CAS:7783-06-4 RTECS #:MX1225000 Other REC Limits:NONE RECOMMENDED OSHA PEL:C, 20 PPM ACGIH TLV:10 PPM/15 STEL; 9394 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE-INHALATION:CNS EFFECTS, RESPIRATORY IRRITATION. EYES:SEVERE IRRITATION. INGESTION:HARMFUL OR FATAL, IRRITATION OF GI TRACT. ASPIRATION INTO THE LUNGS CAN CAUSE SEVERE CHEMICAL PNEUMONITIS, WHICH CAN BE FATAL. SKIN:REPEATED EXPOSURE MAY CAUSE IRRITATION. CHRONIC:DERMATITIS. TARGET ORGANS:SKIN, LUNG, CNS. Explanation of Carcinogenicity:PER NIOSH BULLETIN 50 A POTENTIAL OCCUPATIONAL CARCINOGENIC HAZARD EXISTS DUE TO HUMAN EXPOSURE TO DIESEL EXHAUST. Effects of Overexposure:EYE:IRRITATION, REDNESS, TEARING, BLURRED VISION, CONJUCTIVITIS. SKIN:IRRITATION, DRYNESS, REDNESS, ITCHING. INHAL:HEADACHE, DIZZINESS, DROWZINESS, NAUSEA, VOMITNING, TREMORS, CONVULSIONS, IRREGULAR H EART BEAT. INGESTION: G/I IRRITATION AND SYMPTOMS SIMILAR TO INHALATION. Medical Cond Aggravated by Exposure:EYE, SKIN, HEART, CNS, AND RESPIRATORY DISORDERS MAY BE AGGARAVATED BY OVEREXPOSURE. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INHALATION:REMOVE TO FRESH AIR & RESTORE BREATHING IF NECESSARY. GET MEDICAL ATTENTION. EYE:I MMEDIATELY FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. INGESTION:GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING. NOTHING BY MOUTH IF UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point:125F,52C Lower Limits:0.4% Upper Limits:8.0% Extinguishing Media:CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:EVACUATE AREA. USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT TO FIGHT FIRE. USE WATER SPRAY TO COOL EXPOSED CONTAINERS. DIRECT WATER SPRAY MAY SPREAD FIRE Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG GROUND OR FLOOR, THEN 'FLASH BACK' FROM A DISTANT IGNITION SOURCE. TOXIC FUMES & GASES ARE PRODUCED BY FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR PROTECTIVE EQUIPMENT. SHUT OFF SOURCE IF POSSIBLE & CONTAIN SPILL. REMOVE IGNITION SOURCES. KEEP OUT OF WATER RESOURCES AND SEWERS. ABSORB IN INERT MATERIAL OR RECOVER BY PUMPING. TRANSFER TO DISPOSAL DRUMS. Neutralizing Agent:NONE ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, FLAME. STORE IN WELL VENTILATED AREA. GROUND CONTAINERS DURING TRANSFER. STORE IN CLOSED CONTAINER. Other Precautions:EMPTY CONTAINERS RETAIN RESIDUE. DO NOT PRESSURIZE, CUT, WELD OR EXPOSE TO HEAT, FLAME, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR CONCENTRATIONS EXCEEDING RECOMMENDED LEVEL, USE NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR. FOR SPILL OR IF CONCENTRATION IS UNKNOWN, USE NIOSH/MSHA SUPPLIED AIR RESPIRATOR OR SCBA. Ventilation:GENERAL OR MECHANICAL Protective Gloves:NEOPRENE OR NITRILE Eye Protection:SAFETY GLASSES OR CHEMICAL SPLASH GOGGLE Other Protective Equipment:PROTECTIVE GARMENTS TO PREVENT SKIN CONTACT. Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE WHILE WORKING WITH THIS PRODUCT. Supplemental Safety and Health DANGER! UNTREATED PRODUCT MAY CONTAIN OR RELEASE HYDROGEN SULFIDE. H2S IS A HIGHLY TOXIC AND FLAMMABLE GAS WHICH CAN BE FATAL IF INHALED AT CERTAIN CONCENTRATION. ================== Physical/Chemical Properties ================== HCC:F4 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:325F,163C Vapor Pres:<0.1 PSI Vapor Density:3-7 Spec Gravity:0.84 - 0.93 Viscosity:8 CST @ -4F Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR TO STRAW COLORED LIQUID, KEROSENE ODOR. Percent Volatiles by Volume:NEGLIG ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS, CAUSTICS AND HALOGENS. Stability Condition to Avoid:OPEN FLAMES, SOURCES OF IGNITION, STATIC ELECTRICITY. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND REACTIVE HYDROCARBONS (LDEHYDES, AROMATICS, ETC) COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.