SPRAYON PRODUCTS -- UPSIDE DOWN MARKING PAINTS 03620 CAUTION BLUE -- -
=====================  Product Identification  =====================

Product ID:UPSIDE DOWN MARKING PAINTS 03620 CAUTION BLUE
MSDS Date:07/01/1994
FSC:NIIN:Submitter:N EN
Status Code:A
=== Responsible Party ===
Company Name:SPRAYON PRODUCTS
Address:31500 SOLON ROAD
City:SOLON
State:OH
ZIP:44139
Country:US
Info Phone Num:800-777-2966
Emergency Phone Num:216-292-7400
Resp. Party Other MSDS Num.:94B
CAGE:09800
=== Contractor Identification ===
Company Name:SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.
Address:26300 FARGO AVENUE
Box:City:BEDFORD HEIGHTS
State:OH
ZIP:44146
Country:US
Phone:216-292-7400 OR 216-595-8634
CAGE:09800

=============  Composition/Information on Ingredients  =============

Ingred Name:PROPANE  VP: 760 MM HG
CAS:74-98-6
RTECS #:TX2275000
= Wt:8.
OSHA PEL:1800 MG/M3;1000 PPM

Ingred Name:2-METHYLPROPANE (MFR'S CAS #75-29-5)  VP: 760 MM HG
CAS:75-28-5
RTECS #:TI4300000
= Wt:8.

Ingred Name:NAPHTHA (PETROLEUM), HYDROTREATED HEAVY; (V.M.&P. NAPHTHA) 
    VP: 12 MM HG
CAS:64742-48-9
= Wt:16.

Ingred Name:DISTILLATES (PETROLEUM), HYDROTREATED LIGHT; (MINERAL
    SPIRITS)
CAS:64742-47-8
RTECS #:OA5504000
= Wt:6.

Ingred Name:TOLUENE
CAS:108-88-3
RTECS #:XS5250000
= Wt:11.
OSHA PEL:SEE TABLE Z-2
ACGIH TLV:188 MG/M3;50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

=====================  Hazards Identification  =====================

Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE
    CNTCT, DEPENDING ON CNDTNS OF USE. TO MINIMIZE EXPOS, FOLLOW RECOMS
    FOR PROPER USE, VENT & PPE. ACUTE: IRRIT OF EYES, SKIN & RESP
    SYSTEM. MAY CAUSE NERVOUS SYSTEM D EPRESS. EXTREME OVEREXP MAY
    RESULT IN UNCON & POSSIBLY DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD
    ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPS/SPRAY MISTS. REDNESS
    & ITCHING OR BURNING SENSATION MAY IND ICATE EYE OR EXCESSIVE SKIN
    EXPOSURE. CHRONIC: PRLNGD & RPTD EXPOSURE TO HEXANE MAY CAUSE
    DAMAGE TO NERVE TISSUE OF THE ARMS & LEGS (PERIPHERAL NEUROPATHY),
    RESULTING IN MUSCULAR WEAK & LOSS OF SENSAT ION. THIS EFFECT (EFTS
    OF OVEREXP)
Effects of Overexposure:HLTH HAZS: MAY BE INCREASED BY THE PRESENCE OF
    METHYL ETHYL KETONE. PRLNGD OVEREXP TO SOLVENT INGREDS LISTED MAY
    CAUSE ADVERSE EFFECTS TO THE LIVER, URINARY, BLOOD-FORMING,
    CARDIOVASCULAR & REPRODUCTI VE SYSTEMS. REPORTS HAVE ASSOC RPTD &
    PRLNGD OVEREXP TO SOLVENTS W/PERM BRAIN & NERVOUS SYSTEM DAMAGE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

=======================  First Aid Measures  =======================

First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
    KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP
    AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE.
    EYES:  FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15
    MINUTES. GET MEDICAL ATTENTION. INGEST: NEVER GIVE ANYTHING BY
    MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. GIVE
    SEVERAL GLASSES OF WA TER. SEEK MEDICAL ATTENTION.

=====================  Fire Fighting Measures  =====================

Flash Point Method:PMCC
Flash Point:<-17.8C, 0.F
Lower Limits:0.7%
Upper Limits:12.8%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
    EQUIPMENT . WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG
    NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS
    TO PREVENT PRESSUR E BUILD-UP & POSSIBLE AUTOIGNITION OR EXPLOSION
    WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
    BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. RED LABEL -
    EXTREMELY FLAMABLE, FLASH BELOW 21F.

==================  Accidental Release Measures  ==================

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
    REMOVE WITH INERT ABSORBENT.

======================	Handling and Storage  ======================

Handling and Storage Precautions:NFPA CODE 30B - LEVEL 2 AEROSOLS.
    CONTENTS ARE EXTREMELY FLAMABLE. KEEP AWAY FROM HEAT, SPARKS & OPEN
    FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLOSIVELY. DURING USE
    & UNTIL ALL VAPS ARE GONE: KEE P AREA VENTD - DO NOT SMOKE -
    EXTINGUISH ALL FLAMES, PILOT LIGHTS & HEATERS - TURN OFF (SUPDAT)
Other Precautions:INTENTIONAL MISUSE BY DELIB CONCENTRATING & INHALING
    CONTENTS CAN BE HARMFUL/FATAL. USE ONLY W/ADEQ VENT. AVOID BRTHG
    VAP & SPRAY MIST. AVOID CNTCT W/SKIN & EYES. WASH HANDS AFTER
    USING. THIS COATING  MAY CNTN MATLS CLASSIFIED AS NUISANCE
    PARTICULATES (LISTED "AS DUST" IN INGRED SECTION) WHICH MAY (O THER
    INFO)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
    APPLICABLE LIMITS BY VENT, WEAR  PROPERLY FITTED ORGANIC
    VAPOR/PARTICULATE RESP APPRVD BY NIOSH FOR PROT AGAINS MATLS LISTED
    IN INGRED SECTION. WHEN SANDIN G OR ABRADING DRIED FILM, WEAR
    DUST/MIST RESP APPRVD BY NIOSH FOR DUST WHICH MAY BE GENERATED FROM
    THIS PROD, UNDERLYING PAINT OR ABRASIVE.
Ventilation:LOC EXHST PREFERABLE. GEN EXHST ACCEPTABLE IF EXPOS TO
    MATLS LISTED IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA
    STDS 1910.94, 1910.107, 1910.108.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYE WASH AND DELUGE SHOWER MEETING
    ANSI DESIGN CRITERIA .
Supplemental Safety and Health
HNDLG/STOR PRECS: STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES
    OF IGNIT. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROCS.
    CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCIN OR EXPOSE TO TEMP 
    ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT WATER &
    OTHER HEAT SOURCES COULD CAUSE CNTNR TO (OTHER INFO)

==================  Physical/Chemical Properties  ==================

Boiling Pt:<-17.8C, 0.F
B.P. Text:<0-395F
Vapor Pres:SEE INGREDS
Vapor Density:HVR/AIR
Volatile Org Content %:49
Evaporation Rate & Reference:FASTER THAN ETHER
Percent Volatiles by Volume:>75

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
    MONOXIDE, OXIDES OF METAL LISTED IN INGREDIENT SECTION.

====================  Disposal Considerations  ====================

Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS
    DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40
    CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE
    APPLICABLE EPA HAZARDOUS  WASTE NUMBER. DO NOT INCINERATE.
    DEPRESSURIZE CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STAT
    E AND LOCAL REGULATIONS REGARDING POLLUTION.

===================  MSDS Transport Information  ===================

Transport Information:DOMESTIC OTHER THAN AIR (DOT): SHIPPING NAME:
    INITIATING EXPLOSIVE; HAZARD CLASS: CLASS A EXPLOSIVE; UN/NA
    NUMBER: UN0129; DOT LABEL(S): EXPLOSIVE A; SPECIAL INFORMATION:
    COLLOIDAL LEAD AZIDE - DOT-E  2462; DOT PLACARD: EXPLOSIVES A.
    INTERNATIONAL WATER OR AIR (IMO/ICAO): SHIPPING NAME: IMO: LEAD
    AZIDE; HAZARD CLASS: 1.1A; UN NUMBER: 0129; IMO/CIAO LABEL:
    EXPLOSIVE; SPECIAL INFORMATION: IATA/ICAO;	LEAD AZIDE, WETTED,
    FORBIDDEN.

=====================  Regulatory Information  =====================

SARA Title III Information:INGREDIENTS SUBJECT TO THE REPORTING
    REQUIREMENTS OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
    (SARA) SECTION 313, 40 CFR 372.65 C: XYLENE, ACETONE, BARIUM
    SULFATE.
Federal Regulatory Information:THIS MSDS CONFORMS TO THE HAZARD
    COMMUNICATION STANDARD 29 CFR 1910.1200(G)(4), FOR SIILAR COMPLEX
    MIXTURES. HMIS RATINGS (HEATLH-2; FLAMABILITY-4; REACTIVITY-0).
State Regulatory Information:SEVERAL OF THESE PRODUCTS CONTAIN A
    CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH
    DEFECTS OR OTHER REPRODUCTIVE HARM.

=======================  Other Information  =======================

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 disclaims all liability for its use.  Any person utilizing this
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